At PGConfUS 2017 last week, we presented a talk: Top 10 Problems Solved by PostGIS. The slides for the talk in HTML format and PDF format. The pgRouting examples at the end of the talk seemed to be the most popular.
We'll be giving a pgRouting workshop at FOSS4G Boston 2017 Aug 14-19th where we'll go into much more depth about topics like drive time analysis and Vehicle Route schedule planning (VRP). We also hope to give a talk at FOSS4G 2017 on PostGIS spatial tricks.